2025-10-15 0 הערות

מחקר על טכנולוגיות מיחזור וטיפול מרוכבים עבור 006 אריזה גמישה בנייר אלומיניום

תַקצִיר

006 רדיד אלומיניום (thickness ≤ 0.006mm) is widely used in composite structures of flexible packaging (לְמָשָׁל., PE/aluminum foil/PA, PET/aluminum foil/PE) in the food, תרופות, and electronics industries due to its excellent barrier properties and ductility. אוּלָם, such flexible packaging, characterized by multi-material composition of “aluminum foil-plastic-adhesive”, faces challenges in recycling and treatment, including difficult interface separation, easy aluminum foil loss, and secondary pollution. This paper systematically analyzes the material properties of 006 aluminum foil flexible packaging, elaborates on mainstream recycling and treatment methods such as physical separation, chemical degradation, and physical-chemical combination, examines key technical difficulties, and proposes future development directions based on practical application cases. It aims to provide technical references for promoting the resource recycling of 006 aluminum foil flexible packaging.

 

לְהַכפִּיל 06 מיחזור אריזה רכה של רדיד אלומיניום-4

Eco-a. מָבוֹא

Leveraging the advantages of “קַל מִשְׁקָל + מחסום גבוה”, 006 aluminum foil flexible packaging has an annual consumption of over one million tons in fields such as aseptic food packaging (לְמָשָׁל., dairy pillow packaging), אריזת שלפוחית ​​תרופות, and electronic component shielding packaging. אוּלָם, after disposal, aluminum foil in landfills takes centuries to degrade, while plastic layers easily cause microplastic pollution; incineration releases toxic gases and wastes aluminum resources (the energy consumption of bauxite mining is 20 times that of recycled aluminum). According to data from the China Packaging Federation, the recycling rate of 006 aluminum foil flexible packaging in China was less than 30% ב 2024, נמוך בהרבה מה- 65% recycling rate of ordinary aluminum products. לָכֵן, developing efficient and environmentally friendly recycling and treatment technologies is of great significance for achieving the “פחמן כפול” goals and circular economy.

Eco-b. Material Properties and Recycling Challenges of 006 אריזה גמישה בנייר אלומיניום

א. מאפייני חומר ליבה

  1. מאפיינים של 006 נייר אלומיניום: It has an ultra-thin thickness (0.005-0.006מ"מ) and high purity (≥99.7%). Despite excellent ductility, it has low tensile strength (≤120MPa) and is prone to damage during mechanical processing. A thin Al₂O₃ film (3-5nm thick) is easily formed on its surface due to oxidation, which improves corrosion resistance but affects the subsequent purification efficiency of aluminum resources.
  1. Properties of Composite Structure: The mainstream composite system is “substrate layer (PET/PA) + שכבת רדיד אלומיניום + heat-sealing layer (PE/PP)”, bonded by solvent-based adhesives (לְמָשָׁל., polyurethane adhesives) or co-extrusion compounding processes. ביניהם, polyurethane adhesives have high cross-linking density (gel content ≥85%), strong solvent resistance, and wide temperature resistance range (-40-120℃), becoming the core obstacle to interface separation.

ב. Core Recycling Challenges

  1. Low Interface Separation Efficiency: The interface bonding energy between the adhesive and aluminum foil/plastic layer reaches 20-30J/m². Conventional physical methods are difficult to break the bonding bonds, resulting in incomplete separation of aluminum foil and plastic (separation purity ≤80%).
  1. Severe Aluminum Foil Loss: 006 aluminum foil is thin and brittle, easily causing “aluminum powder loss” (loss rate ≥10%) during crushing and sorting. Its oxidation rate increases by 5%-8% with prolonged processing time.
  1. Risk of Secondary Pollution: In chemical treatment, the volatile volume of solvents (לְמָשָׁל., טולואן, אתיל אצטט) reaches 50-100mg/m³; pyrolysis produces VOCs (לְמָשָׁל., סדרת בנזן) and dioxins (content ≤0.1ng TEQ/m³), requiring additional investment in exhaust gas treatment costs.
  1. Economic Imbalance: עלות תהליכי המיחזור המסורתיים היא בערך 2,000-3,000 RMB/TON, ואילו מחיר המכירה של אלומיניום ממוחזר הוא בלבד 500-800 RMB/טון נמוך מזה של אלומיניום ראשוני, מה שמוביל להתלהבות נמוכה של ארגונים למיחזור.

Eco-C. שיטות מיחזור וטיפול מורכבות עבור 006 אריזה גמישה בנייר אלומיניום

א. שיטת מיחזור פיזי: זיהום נמוך וקנה מידה קל

במרכז “הפרדה מכנית + מיון פיזי”, השיטה הפיזית מתאימה לאריזה גמישה מורכבת עם תוכן דבק נמוך (≤5%). תהליכים אופייניים הם כדלקמן:

  1. Low-Temperature Crushing-Electrostatic Separation Process
  • תַהֲלִיך: Place the flexible packaging in a low-temperature environment (-80~-100℃) to embrittle the plastic layer (glass transition temperature decreases by 20-30℃), then crush it into 5-10mm particles using a hammer crusher; separate aluminum foil (conductor) ופלסטיק (insulator) by an electrostatic separator (voltage 30-50kV) based on their electrical differences.
  • אֵפֶקְט: Aluminum recovery rate ≥85%, plastic purity ≥90%, energy consumption approximately 80-100kWh/ton; אוּלָם, for flexible packaging with high adhesive content, the aluminum foil surface retains adhesive (content ≥3%) after sorting, requiring subsequent polishing.
  1. Thermal Peeling-Briquetting Process
  • עִקָרוֹן: Use infrared heating (120-150℃) to soften the adhesive (viscosity decreases to 1,000-2,000mPa・s), separate the aluminum foil and plastic layer with a roller peeler; press the aluminum foil into aluminum cakes using a briquetting machine (pressure 10-15MPa), and recycle the plastic layer through granulation.
  • יִתרוֹן: Good integrity of aluminum foil (damage rate ≤3), suitable for high-end aluminum foil recycling; disadvantage: high energy consumption (150-200kWh/ton) and easy adhesion of PE heat-sealing layer to the roller.

לְהַכפִּיל 06 aluminum foil soft package recycling02

ב. Chemical Recycling Method: High Purity and Strong Targeting

The chemical method destroys the structure of adhesives or plastics using solvents or reagents to achieve efficient aluminum foil recycling, suitable for high-value-added flexible packaging (לְמָשָׁל., אריזות תרופות):

  1. Solvent Dissolution Method
  • תַהֲלִיך: Use N-methylpyrrolidone (NMP) or dimethylformamide (DMF) as solvents, soak the flexible packaging at 80-100℃ for 2-4h to dissolve polyurethane-based adhesives in the solvent; separate the aluminum foil by filtration, recover the solvent through distillation (שיעור החלמה ≥90%), and dry the plastic layer with water washing before granulation.
  • מַדָד: Aluminum foil purity ≥99.5%, recovery rate ≥95%; אוּלָם, the solvent cost is high (NMP is approximately 15 RMB/kg), and strict control of solvent volatilization is required (occupational exposure limit 200mg/m³).
  1. Acid-Base Catalyzed Degradation Method
  • מִיוּן: Acidic systems (לְמָשָׁל., 10%-15% H₂SO₄, 80-90℃) can degrade polyamide (הרשות הפלסטינית) substrates, while alkaline systems (לְמָשָׁל., 5%-8% NaOH, 60-70℃) can degrade polyvinyl alcohol (PVA) דבקים.
  • בַּקָשָׁה: For PET/aluminum foil/PA flexible packaging, first decompose the PA layer with acid, then degrade the residual adhesive with alkali to finally obtain pure aluminum foil (purity ≥99.2%); אוּלָם, acid-base waste liquid needs neutralization treatment (pH adjusted to 6-8), producing salt residues (בְּעֵרֶך 5%-8% of the processing volume).

ג. Physical-Chemical Combined Method: Efficient Synergy and Cost Balance

Integrating the scalability of physical methods and high purity of chemical methods, the combined method is the current mainstream development direction:

  1. Crushing-Ultrasonic Assisted Solvent Method
  • תַהֲלִיך: Crush the flexible packaging into 2-3mm particles at room temperature, add ethanol-water mixed solvent (volume ratio 3:1), and under the action of an ultrasonic field (power 300-500W, frequency 20-40kHz), the adhesive dispersion efficiency increases by 40%-60%; separate the aluminum foil by centrifugation (recovery rate ≥92%), and dry the plastic particles with hot air (60-70℃) for recycling.
  • יִתרוֹן: Solvent consumption reduced by 30%, processing cycle shortened to 1-2h, cost reduced to 1,500-2,000 RMB/TON. It has been applied on a large scale in a domestic food packaging recycling enterprise (processing capacity 500 tons/month).
  1. Pyrolysis-Melting Separation Method
  • עִקָרוֹן: Pyrolyze the flexible packaging in an oxygen-free pyrolysis furnace (400-500℃) to convert the plastic layer into an oil-gas mixture (usable as fuel) and decompose the adhesive into small-molecule compounds; melt the aluminum foil in a melting furnace (660-700℃), remove the surface oxide layer by adding 3%-5% cryolite as a flux, and cast it into aluminum ingots (purity ≥98.5%).
  • תכונה: No solvent pollution, oil-gas recovery rate ≥70%; אוּלָם, it requires supporting exhaust gas treatment systems (לְמָשָׁל., activated carbon adsorption + catalytic combustion) and high initial equipment investment (בְּעֵרֶך 20 million RMB per production line).

לְהַכפִּיל 06 aluminum foil soft package recycling-3

ד. Technical Parameter Comparison of Mainstream Recycling Methods

To intuitively present the advantages and disadvantages of different methods, the core technical parameters are summarized in the following table:

Recycling Method Type Process Name Core Operating Conditions Aluminum Recovery Rate Plastic Purity צריכת אנרגיה (kWh/ton) עלות עיבוד (RMB/TON) תרחיש יישום
Physical Method Low-Temperature Crushing-Electrostatic Separation Temperature -80~-100℃, Voltage 30-50kV ≥85% ≥90% 80-100 1,200-1,800 Ordinary flexible packaging with adhesive content ≤5%
Physical Method Thermal Peeling-Briquetting Temperature 120-150℃, Pressure 10-15MPa ≥92% ≥88% 150-200 1,800-2,500 Scenarios requiring aluminum foil integrity
Chemical Method Solvent Dissolution (NMP) Temperature 80-100℃, Soaking 2-4h ≥95% ≥92% 50-80 3,000-4,500 Pharmaceutical packaging with high purity requirements
Chemical Method Acid-Base Catalyzed Degradation Acidolysis 80-90℃/Alkalinolysis 60-70℃ ≥94% ≥85% 60-90 2,500-3,500 PET/PA substrate flexible packaging
Combined Method Crushing-Ultrasonic Assisted Solvent Ultrasonic Power 300-500W, Solvent Ethanol-Water 3:1 ≥92% ≥93% 70-110 1,500-2,000 Large-scale food packaging recycling
Combined Method Pyrolysis-Melting Separation Pyrolysis 400-500℃, Melting 660-700℃ ≥90% – 200-250 2,200-3,000 Scenarios requiring no solvent pollution

ECO-D. Analysis of Typical Application Cases

א. Recycling Project of a Domestic Dairy Enterprise

  • Processing Object: PE/aluminum foil/PA aseptic pillow packaging (006 aluminum foil content approximately 15%)
  • Process Route: Low-temperature crushing (-90℃) → Electrostatic separation → Ultrasonic assisted ethanol dissolution → Aluminum foil briquetting → Plastic granulation
  • אֵפֶקְט: Aluminum recovery rate 95.3%, plastic recovery rate 88.7%. Recycled aluminum is used to produce aluminum foil blanks (עֲלוּת 650 RMB/ton lower than primary aluminum), and recycled plastic is used to make packaging pallets, reducing annual CO₂ emissions by approximately 800 טונות.

ב. Technology of a European Pharmaceutical Packaging Recycling Enterprise

  • Processing Object: PET/aluminum foil/PP blister packaging (006 aluminum foil purity 99.9%)
  • Process Route: Supercritical CO₂ extraction (temperature 31℃, pressure 7.38MPa) → Aluminum foil purification → PET recycling
  • יִתרוֹן: Supercritical CO₂ has an adhesive dissolution rate of 98% with no solvent residue. The aluminum foil purity reaches 99.8%, and recycled PET is used to produce pharmaceutical-grade packaging substrates, complying with EU REACH regulations. אוּלָם, the processing cost is approximately 4,000 RMB/TON, suitable only for high-end fields.

ג. Performance Comparison Table of Typical Cases

Case Source Processing Object תהליך ליבה Aluminum Recovery Rate Plastic Recovery Rate Recycled Product Purity Unit Processing Cost (RMB/TON) Environmental Indicator (Annual CO₂ Reduction)
Domestic Dairy Enterprise PE/Aluminum Foil/PA Aseptic Pillow Packaging Low-Temperature Crushing + Ultrasonic Assisted Solvent 95.3% 88.7% Aluminum ≥99.2%, Plastic ≥92% 1,800 800 טונות
European Pharmaceutical Enterprise PET/Aluminum Foil/PP Blister Packaging Supercritical CO₂ Extraction 99.8% 95.0% Aluminum ≥99.8%, PET ≥99% 4,000 500 טונות (small-batch processing)
Domestic Electronic Enterprise* PET/Aluminum Foil/PI Shielding Packaging Pyrolysis-Melting Separation 92.5% – (Pyrolyzed into Fuel) Aluminum ≥98.5% 2,500 1,200 טונות (large-scale processing)

פֶּתֶק: *The case of the domestic electronic enterprise is a supplementary industrial application. The pyrolysis-melting process is used to treat high-temperature resistant flexible packaging containing PI (polyimide), and the plastic layer is pyrolyzed into fuel for energy recovery.

לְהַכפִּיל 06 aluminum foil soft package recycling-1

Eco-e. Future Development Directions and Suggestions

א. Technical Innovation Directions

  1. ר&D of Green Separation Technologies: Develop low-pollution technologies such as enzyme-degradable adhesives (לְמָשָׁל., lipase has a polyurethane degradation rate ≥80%) and plasma surface treatment (breaking the aluminum foil oxide layer) to reduce processing costs.
  1. High-Value Utilization Paths: Use recycled aluminum foil for lithium battery current collectors (requiring purity ≥99.9%) and recycled plastic to prepare antibacterial packaging materials (adding nano-ZnO) to improve the added value of products.

ב. Policy and Industrial Collaboration

  1. Improve the Recycling System: Implement the Extended Producer Responsibility (EPR) מַעֲרֶכֶת, requiring packaging enterprises to bear more than 30% of the recycling costs; establish a three-level network of “community recycling – centralized sorting – professional processing” to improve the raw material recovery rate.
  1. Economic Incentive Measures: Provide a subsidy of 500 RMB/ton for recycled aluminum foil products and exempt recycling enterprises from value-added tax to reduce initial investment risks.

ECO-F. מַסְקָנָה

The recycling and treatment of 006 aluminum foil flexible packaging needs to overcome four core issues: “interface separation – aluminum foil protection – pollution control – איזון עלות”. Physical methods are suitable for large-scale preprocessing, chemical methods can achieve high-purity recycling, and physical-chemical combined methods are the optimal technical path currently. As shown in the table comparison, THE “crushing-ultrasonic assisted solvent process” among combined methods achieves the best balance in cost, recovery rate, וידידותיות לסביבה, and has met the conditions for large-scale promotion. בְּעָתִיד, through technical innovation (לְמָשָׁל., green separation, high-value utilization), policy guidance (לְמָשָׁל., EPR system, subsidy incentives), and industrial collaboration (upstream and downstream industrial chain integration), the recycling rate of 006 aluminum foil flexible packaging should be increased from the current 30% to over 60% עַל יְדֵי 2030, achieving a win-win situation for resource recycling and environmental benefits.

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